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氧化还原沉淀法制备Mn-Ce-Co-Ox/PPS滤料及其低温SCR活性
优质期刊推荐Very short-range interaction of a hydrogen atom and a helium atom
Title:Very short-range interaction of a hydrogen atom and a helium atom
Affiliation:AA(University of London Computer Unit), AB(University of London Computer Unit)
Publication:Proceedings of the Physical Society, Volume 83, Issue 5, pp. 731-738 (1964).
Publication Date:05/1964
Bibliographic Code:
The interaction energy of a hydrogen and a helium atom in the ground
state has been calculated for internuclear distances in the range 0 to 1
A.U., using a two-configuration molecular orbital wave function. The
coefficients E2 and E3 in the expansion
E0 + E2R2 + E3R3
+..., for the electronic interaction energy at small R, where R is the
internuclear distance, have been calculated for the ground states of H +
He, He + He and H + H, using formulae given by Bingel. These formulae
involve the electron charge density of the united atom, and for each
system several different wave functions were used to derive
E2 and E3, and the resulting ratios compared with
another formula derived by Bingel. A recent analysis by Brown and
Steiner suggests that Bingel's expression for E3 should be
doubled, and the fitting of the molecular orbital energies calculated in
this paper tends to support this conclusion. For H + He and He + He a
fitting of the energy has been made for the range of R from 0 to the
zero of the interaction energy, using calculated energies at small R,
the calculated value of E2, the experimental energy of the
united atom and results derived from the scattering experiments.
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